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dc.contributor.authorGogoi, Pradip K-
dc.contributor.authorBorah, Geetika-
dc.contributor.authorBharali, Nayanmoni-
dc.contributor.authorSaikia, Diganta-
dc.description.abstractReaction of RuL₃Cl₃ (L=PPh₃ and AsPh₃) with stoichiometric amount of CS₂ in ethanol-dichloromethane mixed solvent systems at room temperature yields paramagnetic complexes of the type [RuL₂Cl₂(S₂COEt)].The complexes have been characterized by conductance, IR, electronic, ESR spectral, magnetic moment measurement and thermal data as well as by elemental analysis. The appearance of three g-values in the ESR spectra reveal a highly distorted octahedral environment around ruthenium(III) ion with one bidented EtOCS₂⁻ ligand.en_US
dc.relation.ispartofseriesInt. Cl. ⁸ C07F15/00en_US
dc.sourceIJCA Vol.46A(7) [July 2007]en_US
dc.titleSynthesis and characterization of new complexes formed by insertion of carbon disulphide in RuL₃Cl3 (L=PPh₃ and AsPh₃)en_US
Appears in Collections:IJC-A Vol.46A(07) [July 2007]

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