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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.46A [2007] >
IJC-A Vol.46A(07) [July 2007] >
| Title: | Synthesis and characterization of new complexes formed by insertion of carbon disulphide in RuL₃Cl3 (L=PPh₃ and AsPh₃) |
| Authors: | Gogoi, Pradip K
Borah, Geetika
Bharali, Nayanmoni
Saikia, Diganta |
| Issue Date: | Jul-2007 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl. ⁸ C07F15/00 |
| Abstract: | Reaction of RuL₃Cl₃ (L=PPh₃ and AsPh₃) with stoichiometric amount of CS₂ in ethanol-dichloromethane mixed solvent systems at room temperature yields paramagnetic complexes of the type [RuL₂Cl₂(S₂COEt)].The complexes have been characterized by conductance, IR, electronic, ESR spectral, magnetic moment measurement and thermal data as well as by elemental analysis. The appearance of three g-values in the ESR spectra reveal a highly distorted octahedral environment around ruthenium(III) ion with one bidented EtOCS₂⁻ ligand. |
| Page(s): | 1113-1115 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.46A(07) [July 2007]
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