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http://nopr.niscair.res.in/handle/123456789/1225| Title: | Synthesis and characterization of new complexes formed by insertion of carbon disulphide in RuL₃Cl3 (L=PPh₃ and AsPh₃) |
| Authors: | Gogoi, Pradip K Borah, Geetika Bharali, Nayanmoni Saikia, Diganta |
| Issue Date: | Jul-2007 |
| Publisher: | CSIR |
| IPC Code: | Int. Cl. ⁸ C07F15/00 |
| Abstract: | Reaction of RuL₃Cl₃ (L=PPh₃ and AsPh₃) with stoichiometric amount of CS₂ in ethanol-dichloromethane mixed solvent systems at room temperature yields paramagnetic complexes of the type [RuL₂Cl₂(S₂COEt)].The complexes have been characterized by conductance, IR, electronic, ESR spectral, magnetic moment measurement and thermal data as well as by elemental analysis. The appearance of three g-values in the ESR spectra reveal a highly distorted octahedral environment around ruthenium(III) ion with one bidented EtOCS₂⁻ ligand. |
| Page(s): | 1113-1115 |
| URI: | http://hdl.handle.net/123456789/1225 |
| ISSN: | 0376-4710 |
| Appears in Collections: | IJC-A Vol.46A(07) [July 2007] |
Files in This Item:
| File | Description | Size | Format | |
|---|---|---|---|---|
| IJCA 46A(7) (2007) 1113-1115.pdf | 92.43 kB | Adobe PDF | View/Open |
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