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Title: Synthesis and characterization of new complexes formed by insertion of carbon disulphide in RuL₃Cl3 (L=PPh₃ and AsPh₃)
Authors: Gogoi, Pradip K
Borah, Geetika
Bharali, Nayanmoni
Saikia, Diganta
Issue Date: Jul-2007
Publisher: CSIR
IPC CodeInt. Cl. ⁸ C07F15/00
Abstract: Reaction of RuL₃Cl₃ (L=PPh₃ and AsPh₃) with stoichiometric amount of CS₂ in ethanol-dichloromethane mixed solvent systems at room temperature yields paramagnetic complexes of the type [RuL₂Cl₂(S₂COEt)].The complexes have been characterized by conductance, IR, electronic, ESR spectral, magnetic moment measurement and thermal data as well as by elemental analysis. The appearance of three g-values in the ESR spectra reveal a highly distorted octahedral environment around ruthenium(III) ion with one bidented EtOCS₂⁻ ligand.
Page(s): 1113-1115
ISSN: 0376-4710
Source:IJC-A Vol.46A(07) [July 2007]

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