Please use this identifier to cite or link to this item:
Title: Influence of apolar aprotic solvents on proton transfer equilibrium between m-/o-chlorobenzoic acids and the carbinol base of crystal violet: A chemometric analysis
Authors: Shrivastava, Ruchi
Mishra, Sangeeta
Sengupta, Susanta K
Issue Date: Jun-2007
Publisher: CSIR
Abstract: A chemometric analysis of equilibrium results for apolar aprotic solvent effects on proton transfer between m-/o-chlorobenzoic acids and crystal violet carbinol base using Koppel-Palm’s approach shows that the total solvent effect is contributed mainly by dispersion and dipolar/electrostatic interactions in approximately 7:4 ratio. A parallel study with m- and o-fluorobenzoic acids but under conditions favouring acid-acid anion homoconjugation reflects the role of homoconjugated complexed acids in substantially modifying the detailed pattern of solvent effects.
Page(s): 933-936
ISSN: 0376-4710
Appears in Collections:IJC-A Vol.46A(06) [June 2007]

Files in This Item:
File Description SizeFormat 
IJCA 46A(6) (2007) 933-936.pdf70.85 kBAdobe PDFView/Open

Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.