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|Title:||Influence of apolar aprotic solvents on proton transfer equilibrium between m-/o-chlorobenzoic acids and the carbinol base of crystal violet: A chemometric analysis|
Sengupta, Susanta K
|Abstract:||A chemometric analysis of equilibrium results for apolar aprotic solvent effects on proton transfer between m-/o-chlorobenzoic acids and crystal violet carbinol base using Koppel-Palm’s approach shows that the total solvent effect is contributed mainly by dispersion and dipolar/electrostatic interactions in approximately 7:4 ratio. A parallel study with m- and o-fluorobenzoic acids but under conditions favouring acid-acid anion homoconjugation reflects the role of homoconjugated complexed acids in substantially modifying the detailed pattern of solvent effects.|
|Appears in Collections:||IJC-A Vol.46A(06) [June 2007]|
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|IJCA 46A(6) (2007) 933-936.pdf||70.85 kB||Adobe PDF||View/Open|
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