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Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.46A [2007] >
IJC-A Vol.46A(06) [June 2007] >
| Title: | Influence of apolar aprotic solvents on proton transfer equilibrium between m-/o-chlorobenzoic acids and the carbinol base of crystal violet: A chemometric analysis |
| Authors: | Shrivastava, Ruchi
Mishra, Sangeeta
Sengupta, Susanta K |
| Issue Date: | Jun-2007 |
| Publisher: | CSIR |
| Abstract: | A chemometric analysis of equilibrium results for apolar aprotic solvent effects on proton transfer between
m-/o-chlorobenzoic acids and crystal violet carbinol base using Koppel-Palm’s approach shows that the total solvent effect is contributed mainly by dispersion and dipolar/electrostatic interactions in approximately 7:4 ratio. A parallel study with m- and o-fluorobenzoic acids but under conditions favouring acid-acid anion homoconjugation reflects the role of homoconjugated complexed acids in substantially modifying the detailed pattern of solvent effects. |
| Page(s): | 933-936 |
| ISSN: | 0376-4710 |
| Source: | IJC-A Vol.46A(06) [June 2007]
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