Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/12001
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dc.contributor.authorTosh, B-
dc.contributor.authorRoutray, C R-
dc.date.accessioned2011-06-16T13:11:56Z-
dc.date.available2011-06-16T13:11:56Z-
dc.date.issued2011-05-
dc.identifier.issn0975-0991 (Online); 0971-457X (Print)-
dc.identifier.urihttp://hdl.handle.net/123456789/12001-
dc.description234-243en_US
dc.description.abstractPoly (methyl methacrylate) (PMMA) is successfully grafted onto cellulose in homogeneous medium in N,N-dimethyl acetamide/LiCl solvent system. The method is based upon ring opening reaction of cellulose with Ce4+ ion. Ceric ammonium nitrate (CAN) forms free radical on cellulose back bone in presence of DMSO via ring opening mechanism and PMMA is grafted through homogeneous breaking of the acrylic double bond. Methylene blue was used as an inhibitor to check the formation of homopolymer. The graft yield and grafting efficiency was studied by varying reaction time, temperature, and monomer concentration. The products are characterized by FTIR and 1H-NMR analysis and a possible reaction mechanism is deduced. Thermal degradation of the grafted products is also studied by thermo-gravimetric analysis (TG).en_US
dc.language.isoen_USen_US
dc.publisherNISCAIR-CSIR, Indiaen_US
dc.rights CC Attribution-Noncommercial-No Derivative Works 2.5 Indiaen_US
dc.sourceIJCT Vol.18(3) [May 2011]en_US
dc.subjectMethyl methacrylate (MMA)en_US
dc.subjectHomogeneous mediumen_US
dc.subjectN,N–Dimethyl Acetamide/LiClen_US
dc.subjectCeric ammonium nitrate (CAN)en_US
dc.subjectDMSOen_US
dc.subjectGraftingen_US
dc.subjectRing openingen_US
dc.subjectFTIRen_US
dc.subjectGrafting efficiencyen_US
dc.subjectMethylene blueen_US
dc.subjectInhibitoren_US
dc.titleHomogeneous grafting of PMMA onto cellulose in presence of Ce4+ as initiatoren_US
dc.typeArticleen_US
Appears in Collections:IJCT Vol.18(3) [May 2011]

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