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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.50B [2011] >
IJC-B Vol.50B(06) [June 2011] >
| Title: | Ceric ammonium nitrate mediated oxidative dimerisation of 1-methoxy naphthalene |
| Authors: | Ramchander, J
Reddy, A Ram |
| Keywords: | Methoxynaphthalene
CAN
Carbon carbon bond
Binaphthyl
Single electron transfer |
| Issue Date: | Jun-2011 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Nitration of
1-methoxy naphthalene with cerium (IV) ammonium nitrate in acetic acid gives a
complex mixture of six nitro derivatives. Among the six compounds, five are
known earlier and one is an unusual new dimer, 1,1′-dimethoxy-4,4′-dinitro-2,2′-binaphthyl,
formed by the oxidative biradical coupling. The formation of 1,1′-dimethoxy-4,4′-dinitro-2,2′-binaphthyl
is further confirmed by its reduction to 4,4′-diamino-1,1′-dimethoxy-2,2′-binaphthyl. |
| Page(s): | 876-878 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.50B(06) [June 2011]
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