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Title: Ceric ammonium nitrate mediated oxidative dimerisation of 1-methoxy naphthalene
Authors: Ramchander, J
Reddy, A Ram
Keywords: Methoxynaphthalene;CAN;Carbon carbon bond;Binaphthyl;Single electron transfer
Issue Date: Jun-2011
Publisher: NISCAIR-CSIR, India
Abstract: Nitration of 1-methoxy naphthalene with cerium (IV) ammonium nitrate in acetic acid gives a complex mixture of six nitro derivatives. Among the six compounds, five are known earlier and one is an unusual new dimer, 1,1′-dimethoxy-4,4′-dinitro-2,2′-binaphthyl, formed by the oxidative biradical coupling. The formation of 1,1′-dimethoxy-4,4′-dinitro-2,2′-binaphthyl is further confirmed by its reduction to 4,4′-diamino-1,1′-dimethoxy-2,2′-binaphthyl.
Page(s): 876-878
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.50B(06) [June 2011]

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