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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.50B [2011] >
IJC-B Vol.50B(06) [June 2011] >
| Title: | Regioselective NaBH4 and DIBAL-H reductions of 3,4-dimethoxyhomopiperonylphthalimide: Concise and efficient synthesis of nuevamine and isonuevamine |
| Authors: | Wakchaure, Prasad B
Kunte, Sunita S
Argade, Narshinha P |
| Keywords: | N-Homopiperonyl-5,6-dimethoxyhomophthalimide
Regioselective reductions
Intramolecular dehydrative cyclizations
Synthesis
Nuevamine
Isonuevamine |
| Issue Date: | Jun-2011 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Facile synthesis of
nuevamine and isonuevamine has been reported via the regioselective reduction of hindered and unhindered carbonyl
groups of 3,4-dimethoxyhomopiperonylphthalimide, respectively using sodium
borohydride and diisobutylaluminum hydride, followed by an acid catalyzed
intramolecular dehydrative cyclization pathways. The chemistry involved in
obtaining the regioselectivity has been discussed in brief. |
| Page(s): | 868-871 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.50B(06) [June 2011]
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