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IJC-A Vol.50A(06) [June 2011] >


Title: Eutectic mixture-directed kinetics of Diels-Alder reaction
Authors: Nagare, Amit S
Kumar, Anil
Keywords: Cycloaddition
Diels-Alder reaction
Solvent effects
Kinetics
Reaction rates
Viscosity
Carbohydrates
Urea
Dimethylurea
Issue Date: Jun-2011
Publisher: NISCAIR-CSIR, India
Abstract: In the search for environmentally benign solvent media, a new class of solvents composed of mixtures of carbohydrates with urea or methylated urea has been noted to be effective in enhancing the reaction rates of a bimolecular organic reaction like the Diels-Alder reaction of cyclopentadiene with methyl acrylate. The viscosity of these media appears to be an important parameter in controlling the second order kinetics.
Page(s): 788-792
CC License:  CC Attribution-Noncommercial-No Derivative Works 2.5 India
ISSN: 0975-0975(Online); 0376-4710(Print)
Source:IJC-A Vol.50A(06) [June 2011]

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