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Indian Journal of Chemical Technology (IJCT) >
IJCT Vol.14 [2007] >
IJCT Vol.14(5) [September 2007] >
| Title: | Kinetics and mechanism of the hydroxylation of some naphthalene sulphonic acid derivatives by peroxodisulphate |
| Authors: | Abdel-Khalek, Ahmed A
Hassan, Eman S
Hassan, Hala M |
| Keywords: | Oxidation
Oxidation
Peroxodisulphate
Kinetics
Chromotropic acid
1-Amino-4-naphthalene sulphonic acid |
| Issue Date: | Sep-2007 |
| Publisher: | CSIR |
| IPC Code: | C07C7/00 |
| Abstract: | Oxidation of 1,8-dihydroxynaphthalene-3,6-disulphonic acid (CTA) and 1-amino-4-naphthalene sulphonic acid (ANS) by potassium peroxodisulphate leads to hydroxylation of these organic compounds. These oxidations may proceed through inner-sphere electron transfer as in case of ANS or by outer-sphere mechanism in case of CTA. The homolytic fission of S₂O₈²⁻ is the rate determining step in the oxidation of CTA by S₂O₈²⁻, whereas, the intramolecular electron transfer in the precursor compounds is the rate determining step in the mechanism of oxidation of ANS. Hydroxylation takes place in para-position of benzene ring in CTA and ortho-position in ANS. The thermodynamics activation parameters were calculated. Rate of oxidation of both CTA and ANS in methanol-water solvent mixtures is decreased by increasing methanol content in the medium. |
| Page(s): | 466-472 |
| ISSN: | 0971–457X |
| Source: | IJCT Vol.14(5) [September 2007]
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