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Title: Hydrosulfido molybdenum(V) complexes in relevance to xanthine oxidase
Authors: Mitra, Joyee
Sarkar, Sabyasachi
Keywords: Bioinorganic chemistry;Molybdoenzymes;Molybdenum;Xanthine oxidase;Hydrosulfides;Density functional calculations
Issue Date: Mar-2011
Publisher: NISCAIR-CSIR, India
Abstract: The rare and extremely unstable M-SH linkage uniquely prevalent in xanthine oxidase class of enzymes, has been modeled with the relevant Mo(V)-SH moiety in three new complexes. These complexes are characterized fully by X-ray structure analysis, spectroscopic studies and by DFT level of calculations.
Page(s): 401-408
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.50A(03-04) [March-April 2011]

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