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|Title:||Hydrosulfido molybdenum(V) complexes in relevance to xanthine oxidase|
|Keywords:||Bioinorganic chemistry;Molybdoenzymes;Molybdenum;Xanthine oxidase;Hydrosulfides;Density functional calculations|
|Abstract:||The rare and extremely unstable M-SH linkage uniquely prevalent in xanthine oxidase class of enzymes, has been modeled with the relevant Mo(V)-SH moiety in three new complexes. These complexes are characterized fully by X-ray structure analysis, spectroscopic studies and by DFT level of calculations.|
|Appears in Collections:||IJC-A Vol.50A(03-04) [March-April 2011]|
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|IJCA 50A(03-04) 401-408.pdf||316.39 kB||Adobe PDF||View/Open|
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