|
NISCAIR ONLINE PERIODICALS REPOSITORY (NOPR) >
NISCAIR PUBLICATIONS >
Research Journals >
Indian Journal of Chemical Technology (IJCT) >
IJCT Vol.18 [2011] >
IJCT Vol.18(1) [January 2011] >
| Title: | Novel electrochemical synthesis of oxadiazoles at graphite electrode |
| Authors: | Shivaraj, Y
Geetha, A
Shashishekar, T R
Sherigara, B S
Kalluraya, B |
| Keywords: | Electrochemical reduction
Sydnones
Oxadiazoles
Graphite electrode
Voltammetry |
| Issue Date: | Jan-2011 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Electrochemical
methods involve electrons transfer without the use of any oxidizing or reducing
reagents and hence result in the formation of useful and/or novel organic
compounds under mild conditions. In this paper, we report the preparation of 3-substituted-1,2,3-oxadiazole-5-one
derivatives by the electrochemical reduction of 3-arylsydnones on graphite
electrode is reported. The –N=N– moiety in these compounds undergo
electrochemical reduction. Products of the electrolyzed species are isolated by
bulk electrolysis at graphite electrode with a larger surface area. Characterizations
of the reduced products are done by spectral and analytical data. |
| Page(s): | 76-80 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0991 (Online); 0971-457X (Print) |
| Source: | IJCT Vol.18(1) [January 2011]
|
|
