NISCAIR Online Periodicals Repository

Research Journals >
Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.50A [2011] >
IJC-A Vol.50A(01) [January 2011] >

Title: Monodentate bulky trinaphthylphosphine as ligand in Rh, Co and Ru catalyzed hydroformylation of 1-hexene
Authors: Dabbawala, Aasif A
Parmar, Dharmesh U
Bajaj, Hari C
Jasra, Raksh V
Keywords: Catalysis
Monodentate bulky phosphines
Issue Date: Jan-2011
Publisher: NISCAIR-CSIR, India
Abstract: Rhodium, cobalt, and ruthenium complexes of monodentate bulky trinaphthylphosphine ligand, PNp3, have been synthesized and used as catalysts for the hydroformylation of 1-hexene. The catalyst, RhCl(PNp3)3 shows excellent hydroformylation activity as compared to the Co/PNp3 and Ru/PNp3 system. The high conversion (99 %) with high selectivity to aldehydes (97 %) is achieved by RhCl(PNp3)3 catalyst whereas RuCl2(PNp3)3 is more active toward hydrogenation rather than hydroformylation.
Page(s): 27-32
CC License:  CC Attribution- Noncommercial-No Derivative Works 2.5 India
ISSN: 0975-0975(Online); 0376-4710(Print)
Source:IJC-A Vol.50A(01) [January 2011]

Files in This Item:

File Description SizeFormat
IJCA 50A(1) 27-32.pdf225.42 kBAdobe PDFView/Open
 Current Page Visits: 855 
Recommend this item


Online Submission of Articles |  NISCAIR Website |  National Knowledge Resources Consortium |  Contact us |  Feedback

Disclaimer: NISCAIR assumes no responsibility for the statements and opinions advanced by contributors. The editorial staff in its work of examining papers received for publication is helped, in an honorary capacity, by many distinguished engineers and scientists.

CC License Except where otherwise noted, the Articles on this site are licensed under Creative Commons License: CC Attribution-Noncommercial-No Derivative Works 2.5 India

Copyright © 2015 The Council of Scientific and Industrial Research, New Delhi. All rights reserved.

Powered by DSpace Copyright © 2002-2007 MIT and Hewlett-Packard | Compliant to OAI-PMH V 2.0

Home Page Total Visits: 23010 since 01-Sep-2015  Last updated on 13-Oct-2015Webmaster: