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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.50A [2011] >
IJC-A Vol.50A(01) [January 2011] >
| Title: | Monodentate bulky trinaphthylphosphine as ligand in Rh, Co and Ru catalyzed hydroformylation of 1-hexene |
| Authors: | Dabbawala, Aasif A
Parmar, Dharmesh U
Bajaj, Hari C
Jasra, Raksh V |
| Keywords: | Catalysis
Hydroformylation
Monodentate bulky phosphines
Phosphines
Rhodium
Cobalt
Ruthenium
Hexene
Aldehydes |
| Issue Date: | Jan-2011 |
| Publisher: | NISCAIR-CSIR, India |
| Abstract: | Rhodium,
cobalt, and ruthenium complexes of monodentate bulky trinaphthylphosphine
ligand, PNp3, have been synthesized and used as catalysts for the
hydroformylation of 1-hexene. The catalyst, RhCl(PNp3)3
shows excellent hydroformylation activity as compared to the Co/PNp3
and Ru/PNp3 system. The high conversion (99 %) with high selectivity
to aldehydes (97 %) is achieved by RhCl(PNp3)3 catalyst
whereas RuCl2(PNp3)3 is more active toward
hydrogenation rather than hydroformylation. |
| Page(s): | 27-32 |
| CC License: |  CC Attribution- Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Source: | IJC-A Vol.50A(01) [January 2011]
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