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Title: Synthesis and structure of tris (acetylacetonato) aluminum(III)
Authors: Shirodker, Manisha
Borker, Vrinda
Nather, C
Bensch, W
Rane, K S
Keywords: Inorganic chemistry
Aluminum acetylacetonate
Crystal structure
X-ray diffraction
Issue Date: Dec-2010
Publisher: NISCAIR-CSIR, India
Series/Report no.: Int Cl.<sup>9</sup> C01F7/02
Abstract: Tris(acetylacetonato)aluminium(III), [Al(C<sub>2</sub>H<sub>7</sub>O<sub>2</sub>)<sub>3</sub>], a precur-sor in vapor deposition of aluminum oxide, has been prepared starting from industrial alum, Al<sub>2</sub>(SO<sub>4</sub>)<sub>3</sub>.16H<sub>2</sub>O and characterized by chemical, IR, thermal (TG-DSC) and single crystal X-ray diffraction analyses. The compound crystallizes in the monoclinic space group P2<sub>1</sub>/c<i><sub> </sub></i>and all atoms are located in general positions. The central metal is hexacoordinated to three bidentate acetylacetonate ligands.
Description: 1607-1611
ISSN: 0975-0975(Online); 0376-4710(Print)
Appears in Collections:IJC-A Vol.49A(12) [December 2010]

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