Please use this identifier to cite or link to this item: http://nopr.niscair.res.in/handle/123456789/1060
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dc.contributor.authorTripathi, Rashmi-
dc.contributor.authorUpadhyay, Santosh K-
dc.date.accessioned2008-04-17T11:16:22Z-
dc.date.available2008-04-17T11:16:22Z-
dc.date.issued2007-01-
dc.identifier.issn0971–457X-
dc.identifier.urihttp://hdl.handle.net/123456789/1060-
dc.description64-70en_US
dc.description.abstractThe kinetics of palladium(II) catalysed oxidation of ethylenediaminetetraacetic acid (EDTA) by N-bromosuccinimide (NBS) in acidic (HClO₄) as well as in alkaline medium have been investigated. The rate of reaction is always proportional to the concentration of NBS and catalyst. The order of reaction with respect to substrate was also found to decrease from unity to zero in acidic as well as in alkaline medium. The effect of succinimide on the rate of oxidation was negative in each case. In acidic medium, a negligible effect of H⁺ on the rate of oxidation has been observed while in alkaline medium a retarding effect of OH⁻ on the rate has been observed. The proposed mechanism involves the formation of {EDTA-Pdˡˡ} complex which has been verified spectrophotometrically.en_US
dc.language.isoen_USen_US
dc.publisherCSIRen_US
dc.relation.ispartofseriesB01J23/44, C07B33/00en_US
dc.sourceIJCT Vol.14(1) [January 2007]en_US
dc.subjectPalladiumen_US
dc.subjectCatalysisen_US
dc.subjectOxidation of ethylenediaminetetraacetic aciden_US
dc.subjectKinetics of N-bromosuccinimideen_US
dc.titlePalladium(II) catalysis on N-bromosuccinimide oxidation of ethylenediaminetetraacetic acid: A kinetic studyen_US
dc.typeArticleen_US
Appears in Collections:IJCT Vol.14(1) [January 2007]

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