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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.45B [2006] >
IJC-B Vol.45B(04) [April 2006] >
| Title: | Natural kaolinitic clay: A remarkable catalyst for highly regioselective chlorination of arenes with Cl2 or SO2Cl2 |
| Authors: | Jayachandran, B
Phukan, Prodeep
Daniel, Thomas
Sudalai, A |
| Keywords: | Chlorination
chlorine
sulfuryl chloride
aniline
ortho-chloroaniline |
| Issue Date: | Apr-2006 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int.Cl.7 C 07 C |
| Abstract: | Natural kaolinitic clay containing transition metals s as Fe and Ti in its lattice has been found to exhibit unusual regioselectivity in the liquid-phase chlorination of arenes with either Cl2 or SO2Cl2 as the chlorinating agent para-Chlorinated products are predominant for most of the substrates with an exceptional case of ortho-selectivity for the chlorination of aniline. |
| Page(s): | 972-975 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.45B(04) [April 2006]
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