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Title: Epoxidation and oxidation reactions using divinyl benzene crosslinked polystyrene supported t-butyl hydroperoxide
Authors: Sheela, M S
Sreekumar, K
Keywords: Polystyrene supported reagent;epoxidation;oxidation reaction;heterogeneous reaction;polymer analogous reaction
Issue Date: Apr-2006
Publisher: NISCAIR-CSIR, India
IPC Code:  Int.Cl7 C07 D
Abstract: Divinyl benzene (DVB) crosslinked polystyrene supported t-butyl hydroperoxide resin has been prepared and employed in the epoxidation of olefins and oxidation of alcohols. The reagent is found to be efficient as the low molecular weight t-butyl hydroperoxide. Presence of catalyst enhanced the reaction efficiency remarkably. Influence of various reaction parameters such as solvent, temperature and molar excess of the reagent on the reactivity of the polymeric reagent is also being investigated.
Page(s): 943-950
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.45B(04) [April 2006]

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