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Indian Journal of Chemistry -Section B (IJC-B) >
IJC-B Vol.45B [2006] >
IJC-B Vol.45B(04) [April 2006] >
| Title: | Epoxidation and oxidation reactions using divinyl benzene crosslinked polystyrene supported t-butyl hydroperoxide |
| Authors: | Sheela, M S
Sreekumar, K |
| Keywords: | Polystyrene supported reagent
epoxidation
oxidation reaction
heterogeneous reaction
polymer analogous reaction |
| Issue Date: | Apr-2006 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int.Cl7 C07 D |
| Abstract: | Divinyl benzene (DVB) crosslinked polystyrene supported
t-butyl hydroperoxide resin has been prepared and employed in the epoxidation
of olefins and oxidation of alcohols. The reagent is found to be efficient as
the low molecular weight t-butyl hydroperoxide. Presence of catalyst enhanced
the reaction efficiency remarkably. Influence of various reaction parameters
such as solvent, temperature and molar excess of the reagent on the reactivity
of the polymeric reagent is also being investigated. |
| Page(s): | 943-950 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0983(Online); 0376-4699(Print) |
| Source: | IJC-B Vol.45B(04) [April 2006]
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