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Title: Chemoselective hydrazine addition to diethyl 2-(2,3-dioxo-1,3-diarylpropyl)malonates and a tandem deesterification
Authors: Saravanan, Sivaperuman
Purushothaman, Santhanagopalan
Muthusubramanian, Shanmugam
Keywords: 1,2-Ketones;hydrazones;oxidation;chemoselectivity;deesterification;tandem reaction.
Issue Date: Nov-2010
Publisher: NISCAIR-CSIR, India
Abstract: The structural features of the product of the chemoselective reaction of hydrazine on only one of the ketones in a gem diester system with two keto groups by hydrazinium sulfate and hydrazine hydrate are described. A tandem deesterification has also been noticed during the reaction with hydrazine hydrate.
Page(s): 1526-1530
ISSN: 0975-0983(Online); 0376-4699(Print)
Appears in Collections:IJC-B Vol.49B(11) [November 2010]

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