Please use this identifier to cite or link to this item:
|Title:||Synthesis, crystal structure and characterization of an organically templated cobalt phosphate supramolecule|
|Abstract:||A novel organically templated cobalt phosphate supramolecule, [Co(H2O)6]2[HPO4]4·2(C2N2H10), has been synthesized hydro-thermally and characterized by single crystal X-ray diffraction, vibrational spectroscopy, elemental analysis and TGA-DSC. The title compound crystallizes in monoclinic system, space group P2(1)/c, a = 6.27(3) Å, b = 16.367(8) Å, c = 14.736(7) Å, α = 90.00°, β = 91.405(7)°, γ = 90.00°, V = 1512.2(3) Å3, Z = 2. The structure of the title compound consists of four isolated PO3(OH) tetrahedrons, two cobalt complex cation [Co(H2O)6]2+ and two diprotonated ethylenediamine molecules. The PO3(OH) tetrahedrons and cobalt octahedras are linked together via hydrogen bonding interaction, forming an open framework architecture. Protonated ethylenediamine molecules reside in the spacing of the framework and compensate the charge balance.|
|Appears in Collections:||IJC-A Vol.49A(11) [November 2010]|
Files in This Item:
|IJCA 49A(11) 1478-1482.pdf||268.53 kB||Adobe PDF||View/Open|
Items in NOPR are protected by copyright, with all rights reserved, unless otherwise indicated.