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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.49A [2010] >
IJC-A Vol.49A(11) [November 2010] >
| Title: | Synthesis, characterization and properties of a water-rich calcium(II)-4-nitrobenzoate |
| Authors: | Srinivasan, Bikshandarkoil R
Shetgaonkar, Santosh Y
Kohli, Sabeta
Rajnikant |
| Keywords: | Coordination chemistry
Calcium
Nitrobenzoates
Aminopyridines
Water-rich compounds |
| Issue Date: | Nov-2010 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int. Cl.9 C07F1/08 |
| Abstract: | Solid state reaction of [Ca(H2O)4(4-nba)2]
(4-nba = 4-nitrobenzoate) with 2-aminopyridine (2-ap) at 100 °C results in the
formation of an anhydrous compound, [Ca(2-ap)(4-nba)2], while in
aqueous solution, the coordination sphere of Ca(II) in [Ca(H2O)4(4-nba)2]
reorganises in the presence of 2-ap resulting in the formation of a water-rich
Ca(II) compound, [Ca(H2O)6(4-nba)](4-nba)(2-ap)·H2O.
A comparative study of differently aquated 4-nitrobenzoates of Ca(II) is
described. |
| Page(s): | 1468-1477 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Source: | IJC-A Vol.49A(11) [November 2010]
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