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Title: 2-(Naphthyl-⍺-azo)imidazole complexes of manganese(II). Single crystal X-ray structure of [Mn(⍺-NaiEt)₂(NCS)₂] (⍺-NaiEt = 1-ethyl-2-(naphthyl-⍺-azo)imidazole)
Authors: Bhunia, P
Sarker, K K
Lin, C–N
Lu, T–H
Sinha, C
Issue Date: Apr-2007
Publisher: CSIR
IPC Code: Int. Cl. ⁸ C07F13/00
Abstract: Azido/thiocyanato-manganese(II)-naphthylazoimidazole complexes, [Mn(⍺-NaiR)₂(X)₂] (⍺-NaiEt = 1-alkyl-2-(naphthyl-⍺-azo)imidazole; X = N₃-, NCS-), have been characterized. Microanalytical, spectral (FT-IR, UV-vis) and magnetic (bulk and EPR) data have been used to establish the molecular and electronic structure of the complexes. The single crystal X-ray diffraction measurements of [Mn(⍺-NaiEt)₂(NCS)₂] (⍺-NaiEt = 1-ethyl-2-(naphthyl-⍺-azo)imidazole) confirm the tetrahedrally coordinated MnN₄ structure of the complex. Cyclic voltammetry exhibits Mn(III)/Mn(II) couple along with azo reductions.
Page(s): 576-581
ISSN: 0376-4710
Appears in Collections:IJC-A Vol.46A(04) [April 2007]

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