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IJC-A Vol.49A(10) [October 2010] >


Title: Synthesis, crystal structure and photoluminescence property of a Cd(II) framework complex [Cd(2-PTZ)2(H2O)2] {2-PTZ = 5-(2-pyridyl tetrazolate)}
Authors: Singh, Sadhana
Mayer, Peter
Pandey, Ashutosh
Keywords: Coordination chemistry
Hydrothermal synthesis
X-ray crystallography
Photoluminescence
Cadmium
Issue Date: Oct-2010
Publisher: NISCAIR-CSIR, India
IPC CodeInt. Cl.9 C07F3/08; C09K11/00
Abstract: A new 2D supramolecular (hydrogen bonded) Cd(II) network, [Cd(2-PTZ)2(H2O)2]n (2-PTZ = 5-(2-pyridyl) tetrazolate) has been synthesized by hydrothermal reaction and characterized by IR, and X-ray single crystal analysis. In the molecular structure of the studied complex, Cd(II) ion is six-coordinated, which is completed by two water molecules and  two 2-PTZ ligands which provide two nitrogens from the two tetrazolyl groups and two nitrogen atoms from pyridyl rings. The mononuclear units are assembled by intermolecular hydrogen bonding to generate two-dimensional sheets. Photoluminescence spectrum of the polymer complex exhibits strong blue emission at λmax  = 439 nm in the solid state at room temperature.
Page(s): 1345-1348
CC License:  CC Attribution-Noncommercial-No Derivative Works 2.5 India
ISSN: 0975-0975(Online); 0376-4710(Print)
Source:IJC-A Vol.49A(10) [October 2010]

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