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Indian Journal of Chemistry -Section A (IJC-A) >
IJC-A Vol.49A [2010] >
IJC-A Vol.49A(10) [October 2010] >
| Title: | Synthesis, crystal structure and photoluminescence property of a Cd(II) framework complex [Cd(2-PTZ)2(H2O)2] {2-PTZ = 5-(2-pyridyl tetrazolate)} |
| Authors: | Singh, Sadhana
Mayer, Peter
Pandey, Ashutosh |
| Keywords: | Coordination chemistry
Hydrothermal synthesis
X-ray crystallography
Photoluminescence
Cadmium |
| Issue Date: | Oct-2010 |
| Publisher: | NISCAIR-CSIR, India |
| IPC Code: | Int. Cl.9 C07F3/08; C09K11/00 |
| Abstract: | A new 2D
supramolecular (hydrogen bonded) Cd(II) network, [Cd(2-PTZ)2(H2O)2]n
(2-PTZ = 5-(2-pyridyl) tetrazolate) has been synthesized by hydrothermal
reaction and characterized by IR, and X-ray single crystal analysis. In the molecular structure of
the studied complex, Cd(II) ion is six-coordinated, which is
completed by two water molecules and two
2-PTZ ligands which provide two nitrogens from the two tetrazolyl groups and
two nitrogen atoms from pyridyl rings. The mononuclear units
are assembled by intermolecular hydrogen bonding to generate two-dimensional
sheets. Photoluminescence spectrum of the polymer complex exhibits strong blue
emission at λmax = 439 nm in
the solid state at room temperature. |
| Page(s): | 1345-1348 |
| CC License: |  CC Attribution-Noncommercial-No Derivative Works 2.5 India |
| ISSN: | 0975-0975(Online); 0376-4710(Print) |
| Source: | IJC-A Vol.49A(10) [October 2010]
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